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Vol. 4, No. 1 (Winter 2018) 45-51   

Link: http://www.acerp.ir/Vol4/No1/7.pdf
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  Nanostructuring Platinum Nanoparticles on Ni/Ce0.8Gd0.2O2-δ Anode for Low Temperature Solid Oxide Fuel Cell via Single-step Infiltration: A Case Study
F. S. Torknik, G. M. Choi, A. Maghsoudipour and M. Keyanpour-Rad
( Received: September 02, 2018 – Accepted: October 10, 2018 )

Abstract    With the aim of promoting the Ni/Ce0.8Gd0.2O2-δ (Ni/GDC20) cermet anodic performance of low temperature solid oxide fuel cell (LT-SOFC) [1], nanostructuring platinum nanoparticles on NiO/GDC composite was done by single-step wet-infiltration of hexachloroplatinic acid hexahydrate (H2PtCl6.6H2O) precursor on NiO/GDC20 composite. The anodic polarization resistance was measured using symmetric Ni–GDC20|GDC20|Pt electrolyte-supported cell at a temperature range of 400 to 600 °C. Microstructural refinement was studied by field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) techniques in comparison to the bare anode before and after hydrogen reduction at 600 °C and also after anodic performance test. Nanostructuring Pt-nanoparticles with an average particle size of 12.5 nm on Ni/GDC20 anode indicated the lack of electrocatalytic enhancement with the addition of platinum for H2 oxidation reaction in LT-SOFC.


Keywords    LTSOFC, Ni/GDC20 Anode, Platinum Infiltration, Pt-Nanoparticles, H2PtCl6.6H2O


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